钯不对称催化碳碘化反应合成手性二氢苯并呋喃类化合物

以Pd₂dba₃与手性氮膦配体Ld为催化剂,2-甲基烯丙基碘代芳基醚（1）为原料,THF为溶剂,在110 ℃下发生不对称碳碘化反应,合成了一系列手性二氢苯并呋喃类化合物,产率84.1%～94.8%,ee 81%～95%。产物结构经¹ H NMR, ¹³ C NMR和HR-MS( ESI)确证。      

浅析量子混沌教学

介绍了量子力学中量子混沌教学的重要内容和特点,这对帮助学生理解量子力学理论是非常重要的,同时也有利于培养学生的创新能力.     

基于红外吸收光谱的瓦斯气体浓度检测技术

针对现有矿井瓦斯传感器的缺点,基于红外光谱吸收原理,采用差分吸收技术设计了红外瓦斯气体浓度探测系统。该系统采用单光路吸收气室和单光路双波长探测技术,利用差动放大电路为核心的微弱信号处理电路实现瓦斯浓度输出信号的检测,并采用线性关系式拟合瓦斯浓度和输出电压的关系曲线,实现了对瓦斯浓度的全量程精确探测。实验表明,该系统的测量误差小于2%,具有很高的测量精度,具备了煤矿应用的基础。     

Investigation on nonlinear thermo-acoustic characteristics of Rijke tube

Based on the energy conservation relationship,nonlinear thermo-acoustic effects of Rijke tube including instability range,saturation processes and higher harmonics modes were investigated.With coupling between the external flow and the inner space of a Rijke tube, the acoustic characteristics of self-excited oscillation were simulated.The experimental study was also carried out and the results were compared with those from simulation.The nonlinear factors which distort the acoustic waveform distortion were analyzed.From the results,it is seen that varying size of the nozzle outlet changes the acoustic impedance in the boundary, and leads to reduction of the nonlinear effects.The results show that the modes of self-excited oscillation could be influenced by the position of higher harmonics.In the large amplitude oscillation,the distortion of pressure wave within Rijke tube could be induced by the acoustic losses due to vortices on nozzle.It is found that the waveform distortion could be avoided by the shrinkage of nozzle.     

Multi-modal calculations of prompt fission neutrons from 238U（n,f） at low induced energy

Properties of prompt fission neutrons from ²³⁸U(n, f) are calculated for incident neutron energies below 6 MeV using the multi-modal model, including the prompt fission neutron spectrum, the average prompt fission neutron multiplicity, and the prompt fission neutron multiplicity as a function of the fission fragment mass υ(A) (usually named “sawtooth” data) The three most dominant fission modes are taken into account. The model parameters are determined on the basis of experimental fission fragment data. The predicted results are in good agreement with the experimental data.     

大分离条件下风力机叶片三维定常数值模拟研究

为了改善失速条件下风力机气动特性的CFD模拟精度,采用定常的RANS求解方法和一方程S-A湍流模型,数值模拟定桨距型风轮叶片LM19在高风速(18m/s)条件下的气动特性.首先讨论了由流动大尺度分离导致计算收敛曲线大幅度振荡时数值结果的处理方法,然后分析了计算域尺度和网格密度对数值模拟结果的影响,为失速条件下风力机气动...     

Swiss-Roll燃烧器催化剂结构的实验研究

实验研究了装有Pt覆盖的多孔陶瓷的Swiss-Roll燃烧器的燃烧特性,分别得到了3种不同长度的催化剂基底的熄火极限,并测量3种情况下催化剂壁面及催化剂后部空间的温度。实验结果表明,3种情况中,催化剂基底长4.5mm的燃烧器可燃范围最大,所以此长度较适合此Swiss-Roll燃烧器。从温度数据可以看出来,催化剂后部空间存在反应,且受上游催化剂表面反应强度的影响。     

采用直、弯静叶压气机时序效应实验研究

本文实验研究了采用直、弯静叶的某重复级低速压气机在不同时序位置时的总性能及横截面流场特性.在不同流量工况下对压气机整体性能及流场进行了详细测量.结果表明,采用正弯静叶的压气机时序效应相对较弱且喘振裕度有所增加;同时,在压比略有减小的前提下(0.1%级别),凭借消耗扭轴功的大幅F降(3%左右),效率在设计工况下最大可提高...     

HL-2Aװ����CXRS��ϵ�ϵͳ���

为了获取HL-2A等离子体的离子温度、旋转速度及其分布等重要参数,首次在HL-2A装置上开展了CXRS诊断。通过利用能有效探测微弱光的EMCCD和特殊设计的光学采集系统,获得了具有足够信噪比的诊断信号。实验得到的测量信号分析表明,设计是切实可行的。